Oxidative Carbon-Carbon Bond Cleavage by Vanadium Catalyst

The aerobic oxidative CC bond cleavage of vicinal diols catalyzed by vanadium aminotriphenolates is described. Our results show that CC bond cleavag e can be performed in different solvents,under an air or oxygen atmosphere, with a large variety of glycols (cyclic or linear, with aromati c or aliphaticsubstituents) affording the corresponding carbonyl derivatives with high chemoselectivity.Reactions can be performed with as little as 10 ppm of catalyst reaching TON up to 81,000 and TOFs of up to4150 h1. A reaction mechanism, rationalized by de nsity functional theory calculations, is also proposed.


The original dataset source can be reviewed here

This dataset derived results are published in:

Manuscript title: Efficient Vanadium-Catalyzed Aerobic CC Bond OxidativeCleavage of Vicinal Diols

Journal: Adv. Synth. Catal.

DOI: https://doi.org/10.1002/adsc.201800050

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