%nproc=4
%mem=7000MB
#p b97d/gen opt=(modredun) 

Title Card Required

0 1
 C                 -3.12883893   -0.87636912   -0.09340957
 H                 -2.77218450   -1.88517912   -0.09340957
 H                 -2.77216609   -0.37197093   -0.96706107
 H                 -4.19883893   -0.87635593   -0.09340957
 O                 -2.65216401   -0.20226686    1.07418076
 H                 -2.97192271    0.70291500    1.07459690

1 5 S 5 +0.01
L 1 2 5 -1 A

-H -C -O 0
6-31+g*
****